I would say your question is also connected with history of enlargers. Before small formats everything was contact printed.
Take a look on:
https://web.archive.org/web/20110714081658/http://www.rleggat.com/photohistory/history/enlargers.htm
My Grandmother born in 1894 got a job as a girl in a photo lab. I have her contact printing frame. It is a beautiful wooden frame with approx 5x5 window for the print. The glass is broken in the window but it is from a day when all prints were contacted.
For all intents and purposes, it's a distinction without meaning for photographers before 1900. As others have noted, virtually everything printed in the first 50-60 years of photography was a contact print. Early on there were solar enlargers, but they were far from common because they lacked a repeatable, reliable light source that was not prone to igniting the prints. With the advent of electricity and the electric light bulb is when you start to see enlarging being done on a regular basis. To make a meaningful comparison, you'd probably best focus on 20th century practitioners of contact-printing, as they had a choice of method. Andre Kertesz is a good one to look at, as he made most of his early work as contact prints, then grew his print sizes in middle age, and returned to contact printing and Polaroids in his last years.
Can you help point me to some of the most notable LF contact printers? e.g., Edward Weston, Fred Picker?
I am also trying to quantify "why" LF contact prints are considered so special.
If you recall the early days of photography, the Daguerrotype vs Calotype (Daguerre vs Talbot), you would remember that contract printing started way back then and because of that, I would say Talbot would be the most notable contact printer. Of course 'Format' as in 'Large Format' was not applied to the process at that time.
Contact prints are special because they are a positive image and many can be made from the same negative. However, the contact print was at a far disadvantage to the Daguerrotype in terms of sharpness and detail. In fact the Calotype images were described by Talbot himself as "Rembrantish."
Here is an example
"The Open Door" by Talbot, 1843, Salted paper contact print from Calotype negative.
Over time calotypes were refined and some were surprisingly sharp. Baldus used gelatin in his calotype process and produced some amazing salt prints.
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