You will likely get a wide variety of answers to these very broad questions.
I generally use developers as one-shot, disposing of them after use.
I use fixers until they are exhausted.
Stop baths are cheap and I use them as one-shot.
Hypoclear is a one shot.
Photoflo is basically cheap and ideally is a one-shot. But it should be diluted with either distilled, or at least highly filtered water, and since that water is more expensive that the Photoflo itself, I choose to save it for reuse.
I reuse toners until they are exhausted.
Your second question doesn't make a lot of sense - Dektol is a paper developer, while D-76 is a film developer. So you should use the one that is appropriate to what you are doing.