I have Pinhole Assist but have barely used it. It allows selecting f/256 which is well more than close enough for pinhole work. In a quick look it appears to offer steps of 1/3 stop, that's as close as you'll get with a regular manual camera.
What I have done, from back before I had a smart phone, is export a spreadsheet from Pinhole Designer, or create an equivalent, and print it on a little card to stick in my pocket. PD offers a "multiplier" for use with a regular meter reading at f/22. With that you note the shutter speed for f/22 for the film ISO you're using, multiply that time by the multiplier, and cook it down to minutes and seconds, as the multiplier is typically 150 or larger. You can work that sort of thing out from scratch by increasing the f-number one stop and making the shutter speed twice as long, in enough iterations to get close to your pinhole f-stop. I have normally bashed this into a small table so I can take a reading @ f/22, find the corresponding shutter speed in my table and next to that will be the actual exposure time I need.
Where the stuff gets a bit exciting is when you factor in reciprocity failure. That can get pretty serious with some films, e.g., twice the exposure length no longer gives twice the negative density. The aforementioned Pinhole Designer has the ability to include reciprocity compensation for some films. Unfortunately the program is old, ca. 2002 or so, and doesn't have some of today's films. There are also some questions about the reciprocity data for some films anyway, so in essence, there's no substitute for experimenting with the specific material you are using.
Here is a screen snapshot of one of the spreadsheets I describe. You will note the bottom of it is shaded to indicate to me "Don't go there!" I have sometimes joked that among the gear required for pinhole work is a folding chair.
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As I mentioned. there is some question about the reciprocity data! For medium format pinhole, Fuji Acros has relatively low reciprocity failure out to a minute or two which is handy. Most of my recent shooting has been on 8x10 X-ray film, so all bets are off.
Edit: And several replies have happened in the time it took me to fumble this post together, so excuse any redundancy!