I cannot find the type of battery used in the two Braun flashes, so I will assume they are NiCad batteries (well before NiMH or Li ion RECHARGEABLES came into being). If you attempt to charge NiCad, they simply might not accept any charge at all.
If the batteries accept a charge, the second issue might be that the power capacitors have not been 'formed' in a very long time, so they leak their charge rather than storing charge. The capacitors might even fail (go bang), and if that happens the 'magic smoke' is let out and the flash will not work. If the issue is simply leaking capacitors, it may be possible to 're-form' them by simply turning on power from the battery and simply letting the unit sit (not fired) for a hour before powering off the unit leaving it unfired (and maybe repeating that cycle a number of times)