Try a roll without the final rinse to see if the problem originates there. You can always re-wash and final rinse that roll later.
Do you use a changing bag when loading the film on the reels?
I have not experienced it, but I have read that the coatings on some changing bags sometimes deteriorate and can flake off. Since the coatings on some changing bags are reflective I was just wondering if the reflective spots might be bits of coating from the bag? It is kind of a wild guess long shot, but it is something you could check while we are trying to think of a real answer.Yes, I do. Do you think that could be a factor?
The flecks are reflective, which makes we wonder of the fixer or bleach was retained in spots.
Try a roll without the final rinse to see if the problem originates there. You can always re-wash and final rinse that roll later.
I have not experienced it, but I have read that the coatings on some changing bags sometimes deteriorate and can flake off. Since the coatings on some changing bags are reflective I was just wondering if the reflective spots might be bits of coating from the bag? It is kind of a wild guess long shot, but it is something you could check while we are trying to think of a real answer.
Of course, if that is what is happening, you should also check your changing bag for light leaks!
I have a few questions, please.
Would it be possible for you to post an image of the neg showing the reflective spots?
Do you always use a reusable stop between dev and bleach?
I think this could be the solution to your problem as Matt has suggested. IMO most problems with spots and marks on the negatives in C41 processing usually occur in the final rinse/stabilizer stage.
This is the best shot I was able to manage. You can't see the reflective aspect as clearly here, but you can get a sense of what the stuff looks like on the negative:
Thank you for posting the photo of the neg strip.
From looking at your image of the neg strip, I don't think it was the changing bag, unless you can see bits falling off the inside when you open it. !
It looks to me like it's the wash or final rinse.
Did you think of soaking the negs in wark water and just a tiny drop of final rinse. Leave them for a few minutes and then very gently rub the neg between your clean thumb and forefinger and see does that dislodge any of the spots. (don't worry as negs are hardy even when wet ! )
You can dry the neg strips by using a paper clip attached to your drying peg/clip and through the sprocket hole at the top and bottom of the strip.
If you do try it can you let us know how you got on, please?
So I don't have any final rinse on hand, and I won't be able to try this until I get back into my studio, but I just attempted a test with a bit of leader that I clipped from one of the affected rolls and some photo-flo. I rubbed pretty hard but after drying I can still see the material on the emulsion. I also tried earlier with some Pec-12 and a Pec Pad and wasn't able to get any of the stuff off. This is why I was thinking it might have been incomplete fixing, because whatever this is is really hard to remove. It's also possible that it's really embedded in the emulsion.
Editing to add a photo of the film post-rinse, which gives a better view of the substance on the emulsion. It really does look to me like a coating or something that has partially come off?
View attachment 278930
Do the spots rub off if you rub them with your finger or a microfiber cloth? Probably not if they are emulsion damage. But I also noticed in the post #8 image what looked like scratches in the rebate. Odd...
So I don't have any final rinse on hand, and I won't be able to try this until I get back into my studio, but I just attempted a test with a bit of leader that I clipped from one of the affected rolls and some photo-flo. I rubbed pretty hard but after drying I can still see the material on the emulsion. I also tried earlier with some Pec-12 and a Pec Pad and wasn't able to get any of the stuff off. This is why I was thinking it might have been incomplete fixing, because whatever this is is really hard to remove. It's also possible that it's really embedded in the emulsion.
Editing to add a photo of the film post-rinse, which gives a better view of the substance on the emulsion. It really does look to me like a coating or something that has partially come off?
View attachment 278930
I think the opposite is more likely: some chemistry (developer concentrates mainly) tends to crystallize out at low temperatures. It's possible your developer just caught a cold. It's not always possible to redissolve the crystals; you're lucky it worked in your case.My studio space does tend to get pretty hot, since it's located on the top floor of a building without air conditioning, but I don't think it could possibly be hot enough to affect the developer in that way.
So good that you found the cause! I found this one particularly puzzling.
I think the opposite is more likely: some chemistry (developer concentrates mainly) tends to crystallize out at low temperatures. It's possible your developer just caught a cold. It's not always possible to redissolve the crystals; you're lucky it worked in your case.
Do you store your developer replenisher as at working strength or as a concentrate?
Very odd indeed! Do you use tap water by any chance? I can imagine a precipitate forming due to the presence of calcium in the tap water. It wouldn't crystallize though; usually it settles at the bottom as a mikly white/murky layer.
I've had RA4 developer concentrate crystallizing out like crazy, but that's a different situation. I'm surprised C41 developer replenisher is capable of doing the same.
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