I'm working on the same project at the moment. My new darkroom is a large room that we're using as a study with an adjacent bathroom. The wet side is in the shower stall, and the dry side will be in the study. The shower stall will be dedicated for photo use (we have another full bath), but the toilet and sink will still function as intended, and the study will also serve as a study with a desk, bookshelves, and such. I want to black out the whole space so I'll have a roomy open space to print in, even though I won't be using the whole space for darkroom work.
With any solution, I've found it's good to have a couple of different layers, one to block out most of the light, and one to catch all the pinhole leaks, and maybe a third or fourth to make a light trap that lets air pass through.
B&H sells opaque plastic, which I've used to black out small windows. In the current setup I've set up a light trap that lets some air get into the bathroom.
Use gaffer's tape to hang it. Don't use electrical tape. The black plastic will expand and contract, and so will the stretchy electrical tape, and you'll get leaks, and electrical tape outgasses unpleasant substances.
For the big window in the study, I think I'm going to try venetian blinds in the window with blackout curtains made from 16 oz. black commando cloth hanging in front of the window for when I really need it to be totally dark. I just emailed for a quote for the blackout curtains from
www.rosebrand.com, which is a big manufacturer of theatrical curtains, and advertises the fabric itself at a reasonable price. I can sew my own curtains, if it turns out to be really expensive to have them do it, but I figure it's worth getting a quote.