Retaining rings have two faces. The front face, that is supposed to face the lens board, has a centering ridge. The rear face is rounded.
Properly bored lens boards have holes sized so that the centering ridge bears on the inside of the hole. This won't happen if the hole is too large or the board is too thin, as with 2x3 Pacemaker Graphic boards. In these cases, the ridge will bear on the back of the shutter and the shutter will rotate on the board. I think that's where you are.
The solution to your problem is fairly simple. Reverse the retaining ring, i.e., mount it on the shutter with its rounded face to the board. You might also have to put a shim between the rear of the shutter and the board.
You shouldn't have to bend anything.
A Copal #0's iris diameter is 24 mm. This is true of all standard (non-Polaroid) Copal #0 shutters.
Shutters typically have lens-specific aperture scales. If you decide to replace your Copal #0 you may be able to transfer its aperture scale to the replacement shutter. If you're lucky, you may find a used #0 with the right scale for your lens. At worst you'll have to have a new scale made for the replacement shutter. I use SKGrimes for this work.
Copal shutters are no longer made. If you have to buy one, look at dealers, e.g., Igor Camera, on eBay, and post a WTB here.