Nice find! These Spotmatics are robust and easy to use. A couple of comments:
1. If the camera has not been used in a long time, exercise it gently through all the shutter speeds. Do 10s or 100s of exposures. But despite the exercise, it may need a cleaning/checkup.
2. If this is your first time with film, one easy way to get started is to use one of the C-41 films, which can still be developed in many cities. At least in USA, a drug store like Walgreen or CVS will accept C-41 film and send it off to a laboratory. You could use a color print film or one of the two B&W examples: Ilford XP2 or Kodak BW400CN (discontinued but still available via eBay).
3. If you really like the Spotmatic, the Takumar (both Super and SMC multi-coated) lenses are an amazing bargain, considering their optical and mechanical quality.
Good luck, have fun, and feel free to post here again.