Okay, I think I'm getting a little confused here now after the reference to printing via pigments
Junior,
It’s a pity that your first post is caused because you’re in despair…
But I think it is not me to blame but that whole subject is really complicated. Yes, as you I learned those models of subtractive and additive image capture and realease.
But it is best just to regard them as models, nothing more.
As indicated when referring to mechanically printed subtractive images that model of staggered subtractive filters is not totally matched when you look at those spots of dyes. Even less match to that model you will get when that subtracrive print is made with the use of solid, totally opake pigments.
I remember that R.W. G. Hunt has wrote something about that. Also have a look at the theories of Harald Küppers. Perhaps you could find something in his books which makes you feel at ease again.
I guess, that those materials still work according to those models, could be tried to be explained by reflections within the coating and the low resolution of our eyes.
A hexachrome system as you refered to, is used (to my understanding) to compensate for shortcomings in the absorbtion of the inks previously used. Within the ideal scope of colours to be produces such a system would yield a larger area. Again Küppers would be a good reading, he advocates an octachrome system.(
Dead Link Removed, but I rather prefer his books above that site)
To make things even worse there is someome as Edwin Land with his very own theory…
As in life in general putting things into drawers is not always applicable, sometimes they get stuck, sometime one has to relabel them. But they make life so much easier.