The Sodium Bisulphitethat is sold for photographic use is mainly Sodium Metabisulphite, pure Bisulphite is unstable and only available as a laboratory reagent, it's also expensive
Sodium Bisulphite:
Sodium Bisulphite . . . . . . 58 - 99%
Sodium Metabisulphite . . . 1 - 42%
Sodium Metabisulphite:
Sodium Metabisulphite . . . . . . 100%
Sodium Bisulphite . . . . . . . . . < 0.001%
In real terms they are interchangeable but for critical use then 97 parts Metabisulphite are equivalent to 100 commercial Bisulphite, the US manufacture Bisulphite while Europe tends to use Metabisulphite. Kodak Research wrote a paper on the interchangeability and while they aren't exactly the same said either could be used in most applications.
Ian