Most likely the fix was used before the developer, regardless of what appeared to happen. This did not contaminate the fix so it worked fine the next time you used it. The "questionable" mix of Ilfosol will have been destroyed by the stop and fix carryover but, in any case, it is a once-only developer so you will have discarded it.
To check your Ilfosol concentrate, mix a small amount up and drop in the offcut leader of a film roll. It should go black within a few minutes as it is developed - if nothing happened then it is indeed no longer active, but this would be very unusual from a freshly opened bottle of concentrate of course.
Good luck with diagnosing what happened.
EDIT: Seems everyone has typed more-or-less tha same response at the same time . . . . !