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Processing C-41 color print film as a monochrome negative

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David Lyga

Member
Joined
Nov 25, 2007
Messages
3,460
Location
Philadelphia
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processing C-41 color print film as a monochrome negative



First, this thread is NOT about making B&W prints from extant color negatives. Instead, it is about processing C-41 color print film in B&W chemicals in order to create monochrome negatives (which then can be printed onto B&W paper). Twice before, during the past several years, I had written on Photrio about this. But, to tell the truth, every once in a while when I read either Photrio or another photography forum I see that when the question comes up, invariably, the response is that only bad negatives will manifest (i.e., very foggy and of low contrast). Why am I not able to get across? That inability becomes interesting to me.

I think the problem is not endemic to photography. *****
{Moderator's note - we have redacted a small portion of this paragraph because of the inclusion of arguably reasonable points that are in essence, political and controversial outside the area of photography, thus not consistent with the Photrio rules.}
So we have it. For some, truth will forever be subordinate to ... mental inertia? I cannot cure this; I am able only to note this and try to lead the way forward.

Thus, I am asking for moderator approval for yet another iteration of this topic. I guess all that I can hope to be able to do is to instruct the NEWER members, the ones whose minds are not as rigid and are still open to alternative methods. That way they might learn this useful material in order to reap a greater artistic flexibility.

There are two bonuses in store for these newbie trailblazers. First benefit, C-41 color negative film is completely panchromatic, unlike regular B&W film which is only partially so because of its blue bias. Thus, if there are clouds in the sky, no filter is needed in order to capture those clouds. Second benefit, no matter how much age-fog the old color negative film has, ALL that nasty fog will be completely eliminated with this process. Yes, with both new film and old film, you will end up with clean negatives.

I present two extreme examples of films: The Fujicolor negative films I am using for this demonstration are Super G+ ISO 100 and Superia ISO 1600. The '100' is about 20 years old but was always kept frozen and still records at full box speed; thus,I call this film fresh. Since I rate ALL negative films at slightly below box speed, I rate this ‘100’ at EI 64. The 'Superia 1600' is even older, had always been kept at room temperature and, since it also was a far faster film, it is extremely age-fogged. i doubt that it could now even be used to make a color negative, so badly is it fogged. This '1600' film I rate at a lowly EI 32.

For ALL B&W work (negs and paper) I use 80 F (26.7 C).( I have included, below, a temperature factor chart for your convenience, since you probably work at a different temperature.) Simply multiply MY time by the factor for YOUR temperature.

BW Fahr Dev​
65F 2.23​
66F 2.12​
67F 2​
68F 1.9​
69F 1.8​
70F 1.71​
71F 1.62​
72F 1.53​
73F 1.45​
74F 1.38​
75F 1.31​
76F 1.24​
77F 1.17​
78F 1.11​
Factor: 1.055​
79F 1.06​
80F 1​
81F 0.95​
82F 0.9​
83F 0.85​
84F 0.81​
85F 0.77​
86F 0.73​
87F 0.69​
88F 0.65​
89F 0.62​
90F 0.59​
91F 0.55​
92F 0.53​

I developed the '100' film in Dektol (1+9) for 8 minutes. For the '1600' film I developed in Dektol (1+4) also for 8 minutes. (Note that the film that is more age-fogged requires a stronger, less diluted developer.) After development, stop bath, and fixer (fix like you would fix TMAX 400) you are greeted by the ugliest negatives you have ever seen: almost totally black, including the base.

Next, you will use Farmer's Reducer to open these negatives up. Here is how I mix this:

You need: Bleach: 1 mL (or 1 g) potassium ferricyanide for each 25 mL water (this chemical is close to the same for both volume and mass measurement). (NOTE: Keep bleach solution in the dark for continued longevity. (In room light the bleach solution will start deteriorating within one week. I keep my bottle in a black plastic bag used for photo paper.) It is NOT necessary to keep the dry potassium ferricyanide in darkness.

You need: Unused paper strength fixer: (This is the same as fresh film strength fixer, diluted 1 + 1)

Mix BLIX just before use as it will not last for hours: 1 part bleach + 1 part paper strength fixer = 2 parts BLIX.

For the fresh film ('100'): use 20% BLIX: 1 part BLIX + 4 parts water. I usually cut the fixed film into 5 or 6 frame lengths and do this separately in a longer, but narrow, container. (If you cannot see the spacing between frames, blix until the base just becomes visible, then continue to blix each strip separately after cutting.) That way I get to see what is happening and when to stop blixing. (Keep the film fully immersed so as to reduce evenly, and agitate frequently.) After some time (ideally, about 5 to 10 minutes) you will begin to see the orange base begin to emerge. First, it will be a dirty orange, then cleaner, then cleaner yet, then bright orange with no other density. At this point look carefully at the image. because it will be the next to fade if you continue for too long. If the negative has been overexposed, you can continue to let the reducer fade the image a little bit in order to make the negative easier to print. But watch carefully, or you might end up with a weak image. When you take the film out of the blix reducer, plunge it into the original fixer you used when you originally developed the film. If you are happy, wash and dry normally.

For the age-fogged Superia 1600 film: use a stronger BLIX: use 50% BLIX: 1 part BLIX + 1 part water. Follow the same procedure, again ideally, BLIX for 5 to 10 minutes. Shorter blix times are more difficult to manage; longer ones are more tedious. Some films will require full strength blix, i.e., 1 part fix and 1 part bleach, no extra water.

SOME TIPS: I have used extreme examples in order to cover all bases. Your films might be different and you will have to experiment. HOW you experiment will determine your frustration level. I recommend doing this: If you have a roll, the fog/speed of which is unknown to you, instead of shooting the whole roll, cut off the leader almost completely, leaving only a tiny bit you can pull out. Then in total darkness, pull out an inch or two and carefully place/tape it onto your SLR's film aperture gate, close the back, and take one educated guess as to exposure. (Make certain to write it down). I NEVER test whole rolls; that is terribly wasteful. Instead, I do this testing piecemeal, processing the single frame of film in a plastic film cassette-can in total darkness. Using a 10 mL working solution of developer inside the can, I roll the can throughout the development time in a small, tempered water bath. I then take the film out and use tiny trays (1.5"X 2") (bought at Dollar Tree) for stop and fix. You might have to do this several times in order to zero onto the precise exposure and development. It is worth it. If, after you have fully determined what that roll is all about, you load your camera with the remainder of the roll, of course in total darkness, happily knowing that you NOW KNOW that film. Use tape as an aid when loading the film; when attached to the take-up spool, in total darkness, you can get away with wasting only about two frames per loading, as compared to about five frames with 'normal' loading. Film is expensive.

My negative examples are half-frame. The paper was Multigrade IV. The negatives and prints are a bit sharper than they appear here because I might have quavered a bit when I took the pictures with my phone. (Last year I was diagnosed with Parkinson's.) But do persevere with this testing and, soon, you will never understand why you ever had used expensive full rolls of film in order to conduct a single test. – David Lyga
 

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Last edited by a moderator:
Thus, I am asking for moderator approval for yet another iteration of this topic.

No objections - quite the opposite! Please feel welcome and thanks for documenting & sharing your workflow here!

It's been ages since I B&W developed color negative film. I'd have to look up the negatives; all I know is that they printed with difficulty due to the high density to the green + blue channels, and that I used Rodinal (not that it matters much). I did not use a bleach of blix to cut through some of the density and I can see how that might indeed work, especially if a silver filter is involved in the emulsion stack for e.g. antihalation or as a yellow filter. Aged film also increases fog; even though refrigerated, cosmic radiation is a given and will build density esp. on the faster film. I've used refrigerated Superia 200 quite a bit and it is generally very dense indeed - much, much more so than fresh film. Those factors would all add silver density and I can imagine how bleaching would help a bit with that. At the same time it does make me wonder whether the bleach wouldn't also 'attack' shadow detail. Still, can't argue with the prints and negatives you show, which demonstrate that there's ample printable density in your negatives.

I might have missed it, but at what contrast grade did you expose those prints? How did you find the exposure times?

Sorry to hear about the Parkinson's...that's a b*tch for sure. I hope there are ways accessible to you to keep the symptoms at bay as much and as long as possible.
 
Hopefully I understand you. First, adding blix (reducer) to color NEGATIVES will do no good as the image no longer has any silver. Silver IS the image, initially, with color development, but blixing removes all the silver and leaves only the color dye.

However, when processing C-41 in B&W developer there is no color dye. The image remains silver just like with traditional B&W. But, here is the advantage here: For some reason, blixing a C-41 negative developed in B&W developer attacks the base FIRST, not in conjunction with the image. The image seems to POP OUT with a defiance. Only after the base is clean does the image start getting attacked. You can see that my FUJI 1600 film's fog is completely removed, and the image lies INTACT. - David Lyga
 
CONTRAST GRADE: For B&W I use LED light in my Meopta enlarger. But, oddly, with NO filter the prints were a bit too contrasty. I added a #2 filter and found that contrast was lowered one full grade. I have no answer for that since #2 is supposed to be identical to NO filter at all.

Yes the Parkinson's is there but so what? I refuse up to now to take levodopa to mitigate the symptoms but will take things day to day. Otherwise I do feel fine. Thank you. - David Lyga
 
Thanks for the follow-up; yes, we're on the same page!
My hypothesis about the blix working well on the fog and not the image is that the fog might in part consist of a silver-based blue filter, which is relatively high up in the layer stack, so more readily accessible by the blix. However, that's a guess and I don't know, for instance, whether this particular film indeed used a Carey Lea filter in the first place.
 
I had similar results developing some unknown-age found film in d76 then regular fixer then dipped in used C41 blix from an Arista powder kit. It was about 10 years ago. I used the blix until the frame spacing cleared. I remember at the time I mentioned I did that on a Facebook group and was told I was wrong, since the blix erased the image. I said it obviously didn't, since I could see the images. I was told again I was wrong since the blix would dissolve all the silver. Facebook groups kinda suck. Your method sounds much more controllable. I'm including one of the images from that roll here because it suddenly strikes me it's pretty surreal.

img209.jpg
 
Very interesting David! I just recently processed some Agfa CT100 expired in 1988 in rodinal and the negative is very dark. I’m gonna try bleach and fix it to see if this can actually help removing some of the base density. I admire your perseverance in against all odds, you are giving all of us hope!
 
I had similar results developing some unknown-age found film in d76 then regular fixer then dipped in used C41 blix from an Arista powder kit. It was about 10 years ago. I used the blix until the frame spacing cleared. I remember at the time I mentioned I did that on a Facebook group and was told I was wrong, since the blix erased the image. I said it obviously didn't, since I could see the images. I was told again I was wrong since the blix would dissolve all the silver. Facebook groups kinda suck. Your method sounds much more controllable. I'm including one of the images from that roll here because it suddenly strikes me it's pretty surreal.

View attachment 426223

Now, who is correct? You or the "correctors"? This human disconnect is precisely what I was trying to illuminate in the early part of my original post, but, as you can see, the moderators thought that that very truth was a bit too close for comfort and stated that they had edited it out. That is life.

We do live within a world where so called "experts" have decided that they can own anyone he/she chooses. I, like you, have had to deal with these "authorities" many times over in life. Bottom line: What you said would work ... worked. - David Lyga
 
Very interesting David! I just recently processed some Agfa CT100 expired in 1988 in rodinal and the negative is very dark. I’m gonna try bleach and fix it to see if this can actually help removing some of the base density. I admire your perseverance in against all odds, you are giving all of us hope!

Is there anything worth more in this life than to give hope? - David Lyga
 
Now, who is correct? You or the "correctors"? This human disconnect is precisely what I was trying to illuminate in the early part of my original post, but, as you can see, the moderators thought that that very truth was a bit too close for comfort and stated that they had edited it out. That is life.

We do live within a world where so called "experts" have decided that they can own anyone he/she chooses. I, like you, have had to deal with these "authorities" many times over in life. Bottom line: What you said would work ... worked. - David Lyga

David, David, David.
Just because we deleted part of your post due to it being off topic and against the rules here on Photrio doesn't mean that we would necessarily disagree with the content if it were on another site, where it wasn't off topic and wasn't against the rules.
Curation in the interests of site focus and maintenance of civil discussion isn't the same as rejection.
And for clarity, complaints about moderation are only to be brought up directly with the moderation team, or to a very limited extent in the Feedback forum.
 
David, thank you for posting this. There are critics, and then there are contributors. The Internet seems full of the first and lacking the last to great measure.
I find your post adds a great deal to my ignorance. I’m making note of it, and hope to try it out when given a chance to develop again.
Kind regards.
Stay strong. I’m wishing you the best in all.
 
What would be the advantages of doing this compared to XP2 developed in conventional C41?
 
the moderators thought that that very truth was a bit too close for comfort
There was a political remark unrelated to the topic at hand that we removed from your post after someone reported it, as it doesn't align with forum policy. Nothing of your central argument about B&W-processing C41 was touched or even questioned.
 
Interesting topic - one of the kinds I like :smile:
I would very much like a test to restore the color of these samples. Has the ferricyanide destroyed the color couplers in the film, or are they still there?
 
To be honest, I’ve never really thought about what happens when a non-halogenating bleach is applied to color film...
 
Well a non-halo bleach would of course remove image silver and if you then want to go back to color development, you obviously can't. However, since in this scenario only part of the image silver is removed (the undesired fog), you could then bleach again with a halogenating bleach and redevelop in a color developer.
 
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