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Lippmann plates: future potential?

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NiallerM

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This thread {from which the present post was split off} is fascinating stuff. I first came across Lippmann plates maye 10 years ago, and they have often been on my mind in idle moments.

I have a big question about this, so prepare for a bit of a lengthy read. I'll try keep it brief, though.

So, to cases: there is this method of photography which has multiple benefits and also huge significant difficulties asociated with it.

The benefits are: it really produces beautiful results. The results are pure in their representation of colour, and do not vary dependent on pigments or chemical processes, which are sort of arbitrary, and are definitely subjective. The output is cear and should be replicable at any time and place once the conditions of lighting and subject etc are met. Thus, there are few variables to tune. Count this as both a benefit, and an issue in some cases.

A prerequisite of their production seems to be the use of very high resoltion emulsion. Therefore in theory, the process should be future-proof in the sense of any future developments in lens technology which lead to improved resolution power. This is not the case for even digital sensrs at the hiighest end. In fact, if the technique could be modernised, then it would create a master which could be used as a basis for remastering using any emergent digital technologies of the future.

The downsides with the process are obvious: at the moment the process is unweildy in the extreme, involving extreme exposure times, a limited range within which to view the output, the expense, hell, the whole process.

The question I ask is this: Should the Lippmann process be reexamined in the industry with the goal of using newer material technologies in an attempt to introduce it into the market in a form which not simply allows for use in consumer photography, but alo in professional spheres, including film itself?

I ask this because of several issues which may combine to make such a movement viable, to wit:

Dead at Birth?

It is known that several things conspired to ensure that the process never made it to the level of being a marketable commodity. First among these is likely the fact that Autochromes were coming to market at the time. They were relatively easier to use, and they also had all of the energy and backing of the Lumiére brothers, who were approaching the issue of colour plates not as a scientific development existing in a vacuum, but also as a way to make money, and lots of it. That's not to deny the science behind what they achieved. Their product was a fantastic achievement. Lippmann was far more academic, on the other hand, and for him the plates were not a step to market as much as they were a step towrds the creation of holograms. Lippman and the Lumiéres had different motives, and the brothers were first to market. Further research into Lippman plates seems to have effectively halted, and has been only intermittently revisited .

To date, also, there has been no real reason to even consider mounting a challenge to colour repodruction. All the research money went into a method which produces very satisfactory results using dyes of ever-increasing sophistication. Any development of new or even speciality film fell roughly within that paradigm which had been established, and the baton was subsequently picked up in digital formats. There never eally has been a marketable case for looking for an alternative to what we have now.

The State of Play.

So what do we have now? Well, I'd argue that we have created someting of a problem with the move to digital. The most obvious of these is that the digital product can never be improved when newer digital technologies arrive. Yes, they can be remasterd, with interpolation, with "AI", and with other methods, but these all involve creating new data through guesswork, albeit informed guesswork. On the other hand very high resolution physical media can be remastered to the limit of the data the master contains. There is no additive idea at work - the process is simply revealing data which was hitherto latent to the process.

Why Lippmann?

Firstly, it is often a good scientific practice to reexamine old techniques to see if they might have value now, given the progress in other fields. Mutual explotation of new techniques looking for a home, and an old one which has potential for exploiting that progress, can yield results. In this case Lippmann has done the ground work, creating a model, and proving the concept. A new set of hands might realise its true potential.

Why bother?

Market forces, for one. The quality of the product for another. The futureproofing of the product too.

As to why the market would even consider investing in taking the idea forward: major interests include the companies who produce film itself - this has been a very very lucrative market for beasts such as Kodak. By servicing the film industry, they also had a huge market in consumer photography. A new type of stock, which offered extreme resolution, simplified development, the ability to faithfully remaster as and when new digital technologies arrive are selling points. It might also force a change in the optics industry, who have never had real pressure to mass-produce lenses capable of a resolution which need only ever be as fine as the light-sensitive media which is recording it. Also, the film industry itself.

The film industry? Yes. With companies such a Netflix hogging the market, cinemas need new blood. Netflix would seemingly not simply be happy with, but also somewhat reliant on, a purely digital input - one which has led to a degree of sameness of output, and rather insipid photography. They could only be challenged by a product which can only be seen in its proper glory on the big screen. They would have to be content with digital copies of the movie, but even for them there would be a future benefit. If the masters for a film were all in a Lippmann format, then when 12k, 100k, whateverK arrives, they can at least remaster to the very limit of the source.

Oh, I almost forgot - and this could be a major source of investment: when you get into very high-resolution image capture, you also enter into a different market: that of very high-capacity high-speed data archiving. I think that there are some parallel efforts in this field to be opened for exploitation.

What would it take?

Presumably a shitload of research as well as commitments from all parties to collaborate in a large-scale drive to pull it off. Research would need to exploit every new appicable technology. A flexible reflective backing for film to bounce the light off would need to be created. Fine emulsions with great sensitivity would need to be developed. Copying methods would need to be included. Additionally, new optics would be needed. If a suiable refective backing could be creating to support the emulsion, then there would need be only two layers. A requirment of the emulsion would eed to be that it has sufficient surface tension as to remain perfectly flat on the micro-etched backing as not to bleed into the etches.

Is this even possible? I have to think so. It has to be borne in mind that digital photography and, to a lesser etent, analog photography, have been in somehing of a deadly embrace with optics firms. There exists an unspoken pact whereby the two need to march in lockstep when it comes to matters such as resolving power of lenses and sensitivity of sensors. By that I'm not saying they have huddled privately and agreed to cap progress in their fields, rather that neither has faced huge technology pressure to think differently. An interloper such as Lippmann technology would break that unformed cartel. Why should I, as a manufacturer of lenses, produce glass cpable of resolving to 1000 lpmm, when no sensor is capable of reading all that? Likewise, why should I urge the boys in the lab to produce film or digital sensors to give me gigapixel capability when no lens exists to feed it?

To sum up:

Firstly, I have to make it clear that I am not advocating resolution in itself as a good thing - in fact, I'd happily trade in 14 of the megapixels on my Fujifilm XT-5 for a lock button on the EV dial - but there would be some major benefits as I see it to reviving Lippmann:

True colour; no dyes, couplers, etc.
A very high-quality fixed-in-time physical archive which is relatively future-proof.
A differentiator for cinema audiences as against home viewing.
I'll admit it: I subjectively prefer film, so as a consumer I'd give my eye teeth for its potential.
Miniaturisation. Forget the car-sized gear needed for IMax. Given enough resolving power and the optics, you could probably film The Oddyssey in 8mm format!

Sorry for the screed and the rant.
 
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This brings back memories. Lippmann plates are reflection holograms made by incoherent light by placing a mercury mirror directly in contact with the emulsion and taking a photograph using a lens in front of the film in the normal way. This explained why early Daguerreotypists saw colors on their plates, they were inadvertent holographers. The only panchromatic holographic emulsion I can remember was the Kodak 649f so called spectrographic plates. I doubt that these are still available. The limits of Lippmann holograms are the same as all holograms, that you must look at the holographic plate to see the image and projecting them is a type of science fiction, although it has been done experimentally. Holography died a long time ago for many reasons.

Holographic film is not only high resolution, the grain is so small that the film looks like a neutral density filter with invisible, smaller than a wavelength of light, grain and the emulsion needs to be very thick, around 15 microns or so. This makes it very slow and require fairly long exposures. My experimenting was done using dichromated gelatin color sensitized with methylene blue to give it red sensitivity. This material is fairly blue and red sensitive, with some green sensitivity and gave interesting results with very long, around an hour or so, exposure times.

Dichromated gelatin is capable of very high diffraction efficiency holograms due to the way it can be processed that stresses and fractures the gelatin. Unfortunately, these types of phase holograms are not archival, and eventually collapse on exposure to moisture in the air. All of the ones I made 40-50 years ago died and are no longer visible. These holograms had to be sealed in a way that moisture from the air is eliminated from them, not an easy task.

Lippmann motion pictures would be impractical due to the limits of film sensitivity required and difficulty of having a mercury bath that doesn't leak with a moving film, which I would think not possible and quite dangerous. The mercuryy bath is dangerous with still films, let alone moving films. This process is interesting technically, but impractical due to the extremely low light sensitivity of the film required and difficulties in projecting the images. Lippmann holograms are reflection holograms and require front, not rear, illumination. Since they are two dimensional, they likely could be projected, but it would be difficult to get enough light onto them to be brite enough for viewing at high magnification.

Nice idea, but where is the market for this? Technically ultra challenging, but without a market, this won't happen. Despite the eloquent praise of the theoretical, these are doomed to remain in the past as fond memories. Thanks for the fun read that brought back memories.
 
The CA driver licences have Lippmann holograms on them for security reasons.
 
This brings back memories. Lippmann plates are reflection holograms made by incoherent light by placing a mercury mirror directly in contact with the emulsion and taking a photograph using a lens in front of the film in the normal way. This explained why early Daguerreotypists saw colors on their plates, they were inadvertent holographers. The only panchromatic holographic emulsion I can remember was the Kodak 649f so called spectrographic plates. I doubt that these are still available. The limits of Lippmann holograms are the same as all holograms, that you must look at the holographic plate to see the image and projecting them is a type of science fiction, although it has been done experimentally. Holography died a long time ago for many reasons.

Holographic film is not only high resolution, the grain is so small that the film looks like a neutral density filter with invisible, smaller than a wavelength of light, grain and the emulsion needs to be very thick, around 15 microns or so. This makes it very slow and require fairly long exposures. My experimenting was done using dichromated gelatin color sensitized with methylene blue to give it red sensitivity. This material is fairly blue and red sensitive, with some green sensitivity and gave interesting results with very long, around an hour or so, exposure times.

Dichromated gelatin is capable of very high diffraction efficiency holograms due to the way it can be processed that stresses and fractures the gelatin. Unfortunately, these types of phase holograms are not archival, and eventually collapse on exposure to moisture in the air. All of the ones I made 40-50 years ago died and are no longer visible. These holograms had to be sealed in a way that moisture from the air is eliminated from them, not an easy task.

Lippmann motion pictures would be impractical due to the limits of film sensitivity required and difficulty of having a mercury bath that doesn't leak with a moving film, which I would think not possible and quite dangerous. The mercuryy bath is dangerous with still films, let alone moving films. This process is interesting technically, but impractical due to the extremely low light sensitivity of the film required and difficulties in projecting the images. Lippmann holograms are reflection holograms and require front, not rear, illumination. Since they are two dimensional, they likely could be projected, but it would be difficult to get enough light onto them to be brite enough for viewing at high magnification.

Nice idea, but where is the market for this? Technically ultra challenging, but without a market, this won't happen. Despite the eloquent praise of the theoretical, these are doomed to remain in the past as fond memories. Thanks for the fun read that brought back memories.

You correctly highlight the challenges, but I don't think that these are insuperable. It must be remembered that the original plates were really not much more than a proof of concet, and the processes and methods used were not chosen with a view to practicability as to large-scale use. It is at that stage that developent stopped. I gues that is my point.

Clearly, mercury would have to be eliminated from the process, but there are surface reflecting materials out there. The sensitivity is the big iussue clearly, (and I bow to your greater experience in this field), along with, I guess, particle size.

That market is not simpy in image production, buut potentially also in data storage and archival. There are, I believe, efforts being put into that area of data archival onto physical mediua such as film in order to have a physical copy which can survive and electro-magnetic pulse.

I guess ome of this comes back to an observation that sometimes the technical solutions that we live with are not the best, but are those which were either better marketed, or made it into earlier production. There is an inherent paradox here. The better technical direction may not just fall victim to an inferior product because of a rush to the winning post alone; sadly, the superior solution may require such additional refinement as to ensure that we can only ever end up with sub-optimal but acceptable solutions. Those solutions then become embedded through creation of a supporting infrastructure for the inferior product. The outcome becomes self-justifying in time. The superior product ends up on a shelf - a curiosity, in fact.
 
There are, I believe, efforts being put into that area of data archival onto physical mediua such as film in order to have a physical copy which can survive and electro-magnetic pulse.
There are plenty of options for that, some of which are commonly used all over the world - including by billions of consumers.

Alan's question is right:
where is the market for this?
Currently, I'd characterize this as a potential route towards a solution in search for its problem.

There is an inherent paradox here.
Not really. If you look at these cases, there's always a perfectly plausible explanation. Much of it has to do with "best" not being the same as "the best in some particular technical sense", but an overall "best suited to the problem at hand, or just earlier to arrive at the party and fulfill the need, not necessarily technically superior in all respects."

Innovation adoption is of course a complex field, I'll grant you that. Only part of the story is directly related to technology, and insofar it is, that's pretty nuanced as well.

The concepts of Lippmann plates and holography are fascinating for sure. They have their applications and surely, some new ones may arise. For photography and film-making, they've evidently lost out to other, more appealing/practical technologies.
 
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