I don't know much about them, but they are also called "lantern slides" if you search for that on the Net or in a library. The original lantern slides dates from before the time of photography (17thC in Europe at least), and were hand-painted glass plates projected on a screen by the light of some burning device (just like a modern slides projector) . One type of projector invovled a "dissolve" effect between slides, and was called a "stereopticon."
They were a very popular medium, but the arrival of cinema displaced them. Uses ranged from amusement to moral edification in church sermons. The photographic slides were even more popular than the hand painted ones from being much sharper, and those are the ones Jacob Riis (the author of "How the Other Half Lives") used in his crusades on poverty in Lower Manhattan. I just handed in a 20p+ paper on Riis so I'm seeing him everywhere now.
As for assessing their value/rarity, I suppose it can vary a lot, depending on the condition, the subject represented, etc. They were a fairly common medium at the time (I've seen occasionally on eBay boxes of unexposed ones), but having one in good condition now may be of some value. You may want to talk to someone working in archival work. Or somebody from APUG will just step in and demonstrate preternatural knowledge of them, as sometimes happen.
Can you try scanning the one you have? I've never seen one "in person" so I'd be really interested.
Cheers,