Developing B&W transparencies at home

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Molli

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I've been making Black and White Paper Reversals off and on over the past few months, trying to work my way up to doing it with film. I have this irrational idea that the only decent photo I ever take will be part of some experiment I've dreamed up and the emulsion will slide off into the sink or not develop at all or something equally irrevocable. Experimenting with paper leaves me less nervous!

A few days ago I remembered that I have some 2"x3" sheet film so I don't need to risk an entire roll or a full 4"x5" sheet. I'll be using Potassium Permanganate and Sodium Bisulphate rather than dichromate and sulfuric acid. If/when I work up the nerve, I'll let you know how I got on. You may just have provided some much needed motivation.

Black and White Paper Reversal:
 

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George Mann

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OK, I will look at the links. But is there any possible way to develop films such as Fomopan R100 and ADOX Scala without using toxic chemicals?
 

Anon Ymous

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Toxic/caustic chemicals, such as the type of bleach used.

You don't have to use a bichromate bleach, there are alternatives. You also don't have to work with concentrated acids either, you can use more dilute ones in larger quantities. But you have to realise that many of the darkroom chemicals aren't exactly benign and need to be treated accordingly. And I'm not talking about reversal chemicals specifically.
 

Tsubasa

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OK, I will look at the links. But is there any possible way to develop films such as Fomopan R100 and ADOX Scala without using toxic chemicals?

Basically no, because the bleach has to be acidic and a potent oxidizer. Apart from the now banned dichromate (at least in the EU), permanganate is not so toxic (unless you swallow it of course), maybe it stains a lot (but metabisulphite will remove any stains of it). There's also another bleach bath, it's based on cerium but it's way too expensive and it's experimental, done by an old Fuji research paper.

My advice is to stick with a fixed combination: Foma 100R with Foma reversal kit, Adox Scala 50 with the Adox reversal kit.
Both will yield excellent results.
 

relistan

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Basically no, because the bleach has to be acidic and a potent oxidizer. Apart from the now banned dichromate (at least in the EU), permanganate is not so toxic (unless you swallow it of course), maybe it stains a lot (but metabisulphite will remove any stains of it). There's also another bleach bath, it's based on cerium but it's way too expensive and it's experimental, done by an old Fuji research paper.

See my post above. There are other options. Copper sulfate is not too bad and if you use citric acid then the resulting bleach is pretty safe. Household ammonia is not nice but many people have worse cleaning products in their house already.

Alternatively the safest is peroxide bleach (3%) as linked from my blog above.
 
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